I think you are well matched with the 19' of 1/0 relative to the 4' of #6.
You can use this calculator -
http://www.powerstream.com/Wire_Size.htm . Pick wire size, 12V, you length, and pick a current load. Say you use 350 amps as your motor starting requirement:
4' - #6 = 1.3 voltage drop, 10.7 volts at end of circuit
19' - 1/0 = 1.5 voltage drop, 10.5 volts at end of circuit
I think that is plenty fine.